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    • 专利摘要:
    The invention relates to an optical device (100) for a biological or chemical sensor, comprising: - a waveguide micro-resonator (120) arranged to guide a light beam along a closed loop optical path (20); and at least one injection and / or extraction waveguide (110) optically coupled to the micro-resonator for injecting and / or extracting said light beam. According to the invention, the micro-resonator (120) consists of a plurality of elementary waveguides (121) spaced apart from each other and arranged one after the other in a loop-shaped arrangement. The invention makes it possible to increase the sensitivity to the surrounding environment of the microresonator, and therefore of the optical device for a biological or chemical sensor.
    公开号:FR3054664A1
    申请号:FR1657222
    申请日:2016-07-27
    公开日:2018-02-02
    发明作者:Salim Boutami；Boris Taurel
    申请人:Commissariat a lEnergie Atomique CEA；Commissariat a lEnergie Atomique et aux Energies Alternatives CEA；
    IPC主号:
    专利说明:

    DESCRIPTION
    TECHNICAL AREA
    The invention relates to the field of biological or chemical sensors, in particular gas sensors, using a waveguide micro-resonator.
    In such a sensor, a light beam interacts with the biological or chemical medium in which the micro-resonator is immersed.
    This interaction results in optical losses and / or a shift in a resonance wavelength of the micro-resonator, which makes it possible to characterize said biological or chemical medium.
    A concentration is measured, for example a concentration of a gas.
    PRIOR STATE OF THE ART
    An optical device for a nitrous oxide sensor is known in the prior art, as described in the article Sensing nitrous oxide with QCL-coupled silicon-onsapphire ring resonators ”, Clinton J. Smith et al., OPTICS EXPRESS , Flight. 23, No. 5, pp 54915499.
    The optical device described in this article includes an injection and extraction waveguide, and a waveguide micro-resonator.
    The waveguide micro-resonator consists of a curved ring-shaped waveguide, called a ring micro-resonator.
    The curved waveguide has the distinction of not including a sheath. In operation, it is the medium in which the micro-resonator is bathed which acts as a sheath.
    The injection and extraction waveguide consists of a waveguide which extends in a straight line near the ring micro-resonator, parallel to a tangent to the ring.
    In operation, a light beam, called an analysis beam, is sent to the input of the injection and extraction waveguide.
    At a resonance wavelength of the ring micro-resonator, the latter is optically coupled with the injection and extraction waveguide, by evanescent coupling.
    The evanescent coupling corresponds in particular to an interaction between a guided mode of the injection and extraction waveguide, with a guided mode of the micro-resonator, which results in an energy transfer between these two modes.
    The resonance wavelength of the ring micro-resonator is the wavelength for which the phase shift provided by a revolution in the ring is a multiple of 2n.
    Thus, part of the analysis laser beam escapes to the ring micro-resonator, where it performs one or more turns before returning to the injection and extraction waveguide.
    During its passage through the ring micro-resonator, this part of the analysis beam undergoes optical losses, which are due in particular to absorption by the medium surrounding the ring and acting as a sheath. The absorption rate depends on the concentration of nitrous oxide in this medium. The ring can also exhibit radiative losses by curvature, in particular for small radii of curvature (radius of the order or less than the wavelength).
    Thus, the analysis of the light leaving the injection and extraction waveguide makes it possible to determine a rate of loss at the resonance wavelength, and to deduce therefrom a concentration of nitrous oxide.
    A drawback of this device is its low sensitivity, which here corresponds to a small variation in the transmission rate at the resonant wavelength when the composition of the surrounding medium varies.
    An objective of the present invention is to provide an optical device for a biological or chemical sensor, using a waveguide micro-resonator, and having improved sensitivity.
    STATEMENT OF THE INVENTION
    This objective is achieved with an optical device for a biological or chemical sensor, comprising:
    a waveguide micro-resonator, arranged to guide a light beam along a closed-loop optical path; and at least one injection and / or extraction waveguide, optically coupled to the micro-resonator for the injection and / or extraction of said light beam.
    According to the invention, the micro-resonator consists of a plurality of elementary waveguides spaced from each other, and arranged one after the other in a loop-shaped arrangement.
    In operation, the micro-resonator is immersed in the biological or chemical medium to be characterized.
    This biological or chemical medium extends not only around the elementary waveguides, acting as a sheath for each of them, but also in the spaces between two elementary waveguides.
    This increases the volume of interaction between the light circulating in the microresonator and the surrounding biological or chemical environment.
    In other words, there is a lot of energy permeated by the surrounding medium, in particular between the elementary waveguides.
    The sensitivity of the optical device according to the invention is therefore greater than the sensitivity of a similar device in which the micro-resonator would consist of a ring micro-resonator as described in the introduction.
    Preferably, the gain in sensitivity is a factor greater than or equal to three.
    In particular, the invention makes it possible to increase a variation in the absorption by the biological or chemical medium, of a light beam guided in the micro-resonator, when the composition of said medium varies.
    In addition or as a variant, the invention makes it possible to increase a variation in the effective index of the guided mode in the micro-resonator, when the composition of said biological or chemical medium varies. This variation in effective index induces a variation in the resonance wavelength of the micro-resonator. Indeed, the resonance wavelength depends on the effective index of the mode guided in the micro-resonator. For example, for a circular optical path of radius / in the micro-resonator, we have:
    - * N e ^ * 2nR = ητ * 2π (1) with:
    N eff the effective index of the guided mode in the micro-resonator;
    λ the resonance wavelength (wavelength of said guided mode); and m an integer greater than or equal to unity.
    The value of the resonance wavelength can also make it possible to characterize a biological or chemical medium, in particular a liquid medium.
    Preferably, the elementary waveguides are each made of a single material.
    Advantageously, the elementary waveguides all have the same dimensions.
    The elementary waveguides can be distributed periodically one after the other, according to a regular pitch, called the distribution pitch.
    The distribution pitch is advantageously less than the central wavelength of the light beam guided in the micro-resonator.
    Preferably, the distribution pitch is less than:
    λ
    2n h with λ the central wavelength of the light beam guided in the micro-resonator;
    and n h the average refractive index of the elementary waveguides.
    The ratio between the length of an elementary waveguide, and the distribution pitch, is advantageously between 0.40 and 0.60.
    The injection and / or extraction waveguide can be made of the same material as the elementary waveguides.
    Preferably, the elementary waveguides each have the same width, and the width of the elementary waveguides is strictly greater than the width of the injection and / or extraction waveguide.
    The ratio of the width of the elementary waveguides, divided by the width of the injection and / or extraction waveguide, is advantageously between 1.8 and 2.2.
    The width of the elementary waveguides and the width of the injection and / or extraction waveguide can be adapted so that the injection and / or extraction waveguide has a guided mode of effective index equal to the effective index of a guided mode of the micro-resonator, to within 10%.
    Preferably, the micro-resonator and the injection and / or extraction waveguide are spaced from one another.
    The invention also relates to a biological or chemical sensor comprising: a light source, for the emission of a light beam called the analysis beam;
    an optical device according to the invention, in which one of the at least one injection and / or extraction waveguide is arranged to receive the analysis light beam, and to transfer at least one micro-resonator part of the analysis light beam, at a resonance wavelength of the micro-resonator; and at least one photo-detector, arranged to receive a light beam emitted at the output of said optical device, and resulting from the coupling between said injection and / or extraction waveguide and the micro-resonator.
    According to an advantageous embodiment, the optical device comprises an injection and / or extraction waveguide, and:
    the light source is arranged at the input of the injection and / or extraction waveguide; and one of the at least one photo-detector is disposed at the output of the injection and / or extraction waveguide, arranged to receive a signal corresponding to what remains of the analysis light beam after transit through the micro-resonator of at least part of the analysis light beam.
    In addition or as a variant, the optical device comprises an injection waveguide and an extraction waveguide, and:
    the light source is arranged at the input of the injection waveguide; and one of the at least one photo-detector is disposed at the output of the extraction waveguide, arranged to receive a signal corresponding to what remains of the part of the analysis beam transferred to the micro-resonator , after transit through said micro-resonator.
    BRIEF DESCRIPTION OF THE DRAWINGS
    The present invention will be better understood on reading the description of exemplary embodiments given purely by way of non-limiting indication, with reference to the appended drawings in which:
    Figure 1 schematically illustrates a first embodiment of an optical device according to the invention;
    Figure 2 schematically illustrates a variant of the optical device of Figure 1;
    FIG. 3 illustrates a first embodiment of a biological or chemical sensor according to the invention, comprising the optical device of FIG. 2;
    FIGS. 4A and 4B represent a comparison of the sensitivity of a chemical sensor according to the prior art, respectively according to the invention;
    FIG. 5 illustrates a second embodiment of a biological or chemical sensor according to the invention; and FIG. 6 illustrates a method of manufacturing an optical device according to the invention.
    DETAILED PRESENTATION OF PARTICULAR EMBODIMENTS
    FIG. 1 schematically illustrates a first embodiment of an optical device 100 according to the invention.
    The optical device 100 is intended to be part of a biological or chemical sensor as described below.
    In operation, the optical device 100 therefore bathes in a biological or chemical medium.
    The optical device 100 here comprises:
    an injection and extraction waveguide 110, configured to guide a light beam called the analysis beam; and a waveguide micro-resonator 120, configured to guide at least a portion of the analysis beam along an optical path 20 in closed loop.
    According to the invention, the waveguide micro-resonator 120 consists of a plurality of waveguide sections, called elementary waveguides 121.
    The elementary waveguides 121 together define the optical path 20 traveled by the light in the micro-resonator, here a circular optical path 20 (shown in dotted lines in FIG. 1). In other words, they are arranged one after the other in a ring-shaped arrangement.
    The several elementary waveguides are spaced from each other.
    In other words, the input of an elementary waveguide is not in direct physical contact with the output of a neighboring elementary waveguide.
    The elementary waveguides are separated two by two by a respective free space 122.
    In operation, these free spaces 122 are occupied by the biological or chemical medium in which the micro-resonator 120 is bathed.
    Each of the elementary waveguides 121 is devoid of sheath, so that in operation, it is the biological or chemical medium in which they bathe which acts as sheath.
    Each elementary waveguide 121 is therefore advantageously made of the same single material.
    This material is the same for all the elementary waveguides 121.
    The elementary waveguides are advantageously made of silicon or of silicon nitride.
    They are for example made of silicon, to guide a light beam in the infrared (wavelength greater than 1 μm, in particular between 1 μm and 10 μm).
    As a variant, the elementary waveguides 121 are made of nitride, in particular silicon nitride (S13N4), to guide a light beam in the visible range (wavelength strictly less than 1 μm, in particular between 0.4 pm and 0.8 pm).
    It can be considered that the micro-resonator 120 forms a segmented ring micro-resonator, that is to say a micro-resonator as described in the introduction, in which only certain sections of the curved waveguide are preserved, and form the elementary waveguides.
    In operation, the light guided in the micro-resonator 120 partly extends into the surrounding biological or chemical medium when it passes through an elementary waveguide 121, said medium forming the sheath of this elementary waveguide 121.
    In addition, the light guided in the micro-resonator 120 extends entirely in the surrounding biological or chemical medium when it crosses a free space 122, passing from one elementary waveguide 121 to the next.
    Consequently, the influence of the biological or chemical medium on the light guided in the micro-resonator 120 is high, greater than its influence in a ring microresonator as described in the introduction.
    This stronger influence is reflected in particular by a greater variation in the absorption by said medium, when the composition of said medium varies.
    When the refractive index of a component of the biological or chemical medium is high, for example greater than 2, a variation in the concentration of this component in said medium results in a large variation in the refractive index. This variation in refractive index is found in the phase shift provided by a revolution in the microresonator, and therefore in the value of the resonance wavelength of the micro-resonator. Thus, the strongest influence of the surrounding medium, in a micro-resonator according to the invention, can also result in a greater variation in the value of the resonant wavelength, when the composition of said medium varies.
    The invention thus makes it possible to increase the sensitivity to the surrounding environment of the microresonator, and therefore of an optical device and of a biological or chemical sensor according to the invention.
    The micro-resonator 120 is placed near the injection and extraction waveguide 110.
    At the micro-resonator 120, the injection and extraction waveguide 110 extends in a straight line, parallel to a tangent to the micro-resonator.
    The injection and extraction waveguide 110 extends outside the microresonator 120, without necessarily having direct physical contact with the latter.
    In the following, an example is illustrated, but not limited to, in which the injection and extraction waveguide 110 is spaced from the micro-resonator 120.
    The micro-resonator 120 and the injection and extraction waveguide 110 are optically coupled to each other by evanescent coupling.
    In operation, the injection and extraction waveguide 110 receives at the input a light beam called analysis.
    At least part of the analysis beam is transferred into the waveguide micro-resonator 120, by evanescent coupling.
    The part of the analysis beam transferred into the waveguide micro-resonator 120 is a signal at a resonance wavelength of the micro-resonator 120.
    It can be all or part of the analysis beam.
    The resonance wavelength of the micro-resonator is the wavelength for which the phase shift provided by a revolution in the micro-resonator is a multiple of 2n.
    The part of the analysis beam transferred into the micro-resonator therefore forms the light beam guided by the micro-resonator. In other words, this part of the analysis beam corresponds to the light guided in the micro-resonator 120, subjected to the influence of the external environment, here the biological or chemical medium in which the micro-resonator bathes.
    In the example illustrated in FIG. 1, the device 100 comprises a single injection and extraction waveguide.
    Thus, at least part of the analysis beam is transferred from the injection and extraction waveguide 110 to the waveguide micro-resonator 120, where it performs several turns before returning to the same waveguide. injection and extraction wave 110.
    As detailed below, all the light does not return to the injection and extraction waveguide 110, due to losses during propagation in the microresonator 120. These losses can even be 100%.
    Preferably, the injection and extraction waveguide 110 is made, like the elementary waveguides 120, of a single material, the surrounding biological or chemical medium acting as a sheath.
    This single material is advantageously the same as the material constituting the elementary waveguides.
    The advantageous rules for sizing the optical device 100 are detailed below.
    The micro-resonator, here in the form of a ring, advantageously has an external radius less than or equal to 10 μm, in particular less than or equal to 5 μm.
    Preferably, all the elementary waveguides have the same shape and the same dimensions.
    The shape of an elementary waveguide 121 is here a portion of a right cylinder with an annular base, this portion being delimited by two planes 123 receiving the generatrix of the cylinder and together defining an angle a.
    Each elementary waveguide 121 is characterized by a height, a width w and a length l (here l is a curvilinear length, measured at the center of the elementary waveguide).
    The different elementary waveguides 121 are distributed periodically one after the other, according to a regular pitch P, called the distribution pitch.
    Here, the pitch P denotes a curvilinear length, corresponding to the curvilinear length of an elementary waveguide 121 and a free space 122. It is in other words the curvilinear length of a portion of the optical path 20, followed by light in the center of an elementary waveguide 121 and in the adjacent free space 122.
    So that the structure in independent elementary waveguides does not affect the light beam guided in the micro-resonator, the pitch P is less than the central wavelength of this light beam.
    On this scale, light is only sensitive to an average refractive index between the index of elementary waveguides 121 and the index in free spaces 122, and is not diffracted.
    In other words, the core of the micro-resonator 120 behaves like a material with an average refractive index:
    moy = -ni + p-i ni (2) with:
    l the curvilinear length of an elementary waveguide;
    P the distribution pitch of the elementary waveguides;
    n h the average refractive index in an elementary waveguide; and n b the average refractive index between two elementary waveguides, that is to say the average refractive index of the biological or chemical medium surrounding the elementary waveguides.
    Preferably, the step P checks in particular:
    (3) λ
    2n avg with:
    λ the central wavelength of the light beam which propagates in the microresonator, or in other words the resonance wavelength of the micro-resonator.
    We even have advantageously:
    (4) with:
    n h the average refractive index in an elementary waveguide.
    Here, the elementary waveguides are made of one and the same material, therefore n h is the refractive index of the elementary waveguides.
    In practice, the distribution pitch P is advantageously less than 3 μm, and even less than 2 μm, or even 1 μm.
    According to the invention, the micro-resonator 120 has a guided mode of effective index substantially equal to the effective index of a guided mode of the injection and extraction waveguide 110, preferably exactly equal.
    By substantially equal is meant equal to plus or minus 1% close, or even to plus or minus 5% close or even to plus or minus 10% close.
    As a reminder, the effective index of a mode, in particular the effective index of a mode guided by a waveguide, is defined as follows:
    N eff - β ( 5 ) with:
    N e ff the effective index of the mode considered;
    λ the wavelength of the light beam propagating in the waveguide; and β the phase constant of the waveguide.
    The phase constant β depends on the wavelength and on the mode of the light beam propagating in the waveguide, as well as on the properties of this waveguide (in particular refractive indices and geometry).
    The phase constant β is defined by: A (z) = A (0) exp (yz), where z is an abscissa along a propagation path in the waveguide, A (z) is the complex amplitude in function of z of a light beam propagating in the waveguide, and β is the imaginary part of y.
    We can sometimes consider that the effective index designates the average optical index of the medium as it is "seen" by a mode of the light beam propagating in the waveguide.
    Preferably, the mode guided in the micro-resonator, respectively in the injection and extraction waveguide, is a zero order mode, generally quasigaussian (fundamental mode).
    The injection and extraction waveguide 110 being formed in one piece, and the micro-resonator 120 being formed segmented, the above condition on the effective indices of the guided modes advantageously results in a condition on the widths respective of the injection and extraction waveguide 110 and of the elementary waveguides 121.
    Advantageously, we have:
    w> W (6) with:
    w the width of an elementary waveguide 121, measured in a plane orthogonal to the optical path 20 traversed by the light in the micro-resonator 120; and
    W the width of the injection and extraction waveguide 110, measured in a plane orthogonal to the optical path traveled by the light in the injection and extraction waveguide 110.
    In practice, each elementary waveguide 121 preferably has a rectangular section of height h ± and of width w, in planes orthogonal to the optical path 20 traveled by the light in the micro-resonator 120. In the same way, the injection and extraction waveguide 110 advantageously has a rectangular section of height h ± = h 2 and of width W, in planes orthogonal to the optical path traveled by the light in the injection and extraction waveguide 110 .
    Equation (6) is notably verified when the injection and extraction waveguide 110 is made of the same material as the elementary waveguides 121, and therefore has the same refractive index.
    The widths w and VF making it possible to verify the above condition on the effective indices of the guided modes, can be calculated with precision using electromagnetic simulation tools known to those skilled in the art. These simulation tools can be used to adjust the various parameters of the optical device 100, so as to verify said condition. These parameters are in particular geometric parameters (no distribution P, curvilinear length l of an elementary waveguide), and refractive index values (refractive indices of the injection and extraction waveguide and index elementary waveguides).
    In particular, an optimal value of the ratio between the widths w and VF can be determined.
    The ratio of the width w divided by the width VF is substantially equal to 2, advantageously between 1.9 and 2.1, and even between 1.8 and 2.2.
    Preferably, the ratio between the curvilinear length Z of an elementary waveguide and the distribution pitch P is substantially equal to 0.5. In particular, this ratio is advantageously between 0.4 and 0.6, or even between 0.45 and 0.55, or even exactly equal to 0.5.
    In other words, the free spaces have about the same curvilinear length as the elementary waveguides, which corresponds to the best technological compromise since neither the elementary waveguides nor the free spaces have to be too large. reduced.
    Preferably, there is both a ratio of about 0.5 between the curvilinear length l and the pitch P, and a ratio of the width w divided by the width IV substantially equal to 2.
    FIG. 2 schematically illustrates a variant of the optical device of FIG. 1.
    The optical device 100 ′ illustrated in FIG. 2 differs from the device in FIG. 1 only in that the elementary waveguides 121 ′ of the micro-resonator 120 ′ each have the shape of a rectangular parallelepiped.
    The dimensions of an elementary waveguide are defined in particular by the length l, which in this case is no longer curvilinear.
    The distribution pitch of the elementary waveguides 121 'being reduced, preferably less than 2 μm, the optical path of the light guided in the micro-resonator 120' can be assimilated to a circular optical path.
    According to this variant, the injection and extraction waveguide 110 ′ preferably extends parallel to one of the elementary waveguides 12Γ.
    FIG. 3 illustrates a first embodiment of a biological or chemical sensor 1000 according to the invention, comprising an optical device according to the invention, here the optical device 100 'of FIG. 2.
    Such a sensor forms, for example, but not limited to, a gas sensor, for measuring the concentration of a predetermined gas in a medium, called a chemical medium.
    The sensor 1000 according to the invention comprises:
    a light source 200, adapted to the emission of a light beam said analysis beam 1200, preferably a laser, adapted to the emission of a monochromatic beam;
    the device 100 '; and a photo-detector 300, adapted to measure the light intensity of an incident beam.
    The analysis beam 1200 is centered here on a wavelength of approximately 4320 nm.
    The light source 200 is disposed at the input of the injection and extraction waveguide 110 ′, that is to say close to a first end thereof, for the injection of the analysis beam 1200 in said waveguide 110 '.
    The analysis beam 1200 propagates in the injection and extraction waveguide 110 ', up to the proximity of the micro-resonator 120', where at least a portion 1220 of the analysis beam enters the micro-resonator and performs several laps there.
    According to a first embodiment, the analysis beam 1200 is a monochromatic beam, centered on the resonance wavelength of the micro-resonator 120 ′, and of spectral width less than or equal to 10 nm. In this case, the part 1220 of the analysis beam which enters the micro-resonator 110 ′ in fact corresponds to the whole of the analysis beam 1200.
    As a variant, the analysis beam is a broad spectrum beam, of spectral width greater than 10 nm, for example greater than 100 nm. In this case, the part 1220 of the analysis beam which enters the micro-resonator 110 'corresponds to a spectral selection of the analysis beam, centered on the resonance wavelength of the microresonator 120'.
    During its transit through the micro-resonator 120 ′, said part 1220 of the analysis beam undergoes losses which are due:
    the curvature of the optical path, causing losses to radiative modes;
    possibly, the roughness of the elementary waveguides (minor losses); and above all, absorption by the surrounding biological or chemical environment.
    The absorption by the surrounding biological or chemical medium is all the more important, as said part 1220 of the analysis beam is confined for a significant period (due to the several turns) in a compact component (the micro-resonator).
    In addition, the clever structure of the micro-resonator according to the invention further increases the absorption by the surrounding medium.
    Said part 1220 of the analysis beam then returns to the injection and extraction waveguide 110 ′, minus the losses linked to transit in the micro-resonator 120 ′. As detailed above, the return to the injection and extraction waveguide 110 ′ is also done by evanescent coupling.
    The light beam 1300 at the outlet of the injection and extraction waveguide 110 ′ therefore corresponds to the analysis beam 1200, minus the losses in the micro-resonator.
    Among the several types of losses listed above, only absorption by the surrounding biological or chemical medium varies greatly depending on the composition of this medium.
    Consequently, the analysis of the light beam 1300 at the output of the injection and extraction waveguide 110 'makes it possible to obtain information on said biological or chemical medium, for example a concentration of a gas of interest.
    This analysis is carried out by means of the photo-detector 300, placed at the outlet of the injection and extraction waveguide 110 ′, that is to say close to a second end thereof, to receive the beam. light 1300 emerging from said waveguide 110 ′.
    Preferably, the distance between the injection and extraction waveguide 110 ′ and the micro-resonator 120 ′ according to the invention is adapted so that the transmission by the optical device according to the invention, at the length of resonance wave of the microresonator, or minimum for a zero concentration of this gas of interest in the surrounding medium.
    We commonly speak of “critical coupling” to designate the coupling associated with this minimum transmission, corresponding for example to a transmission rate of less than 10%.
    Then, the transmission at the resonance wavelength of the micro-resonator is all the more important as the concentration of gas of interest in the surrounding medium is high.
    In practice, the critical coupling is achieved for a distance between the injection and extraction waveguide and the micro-resonator, less than the distance associated with the critical coupling in a device according to the prior art as described in the introduction.
    According to the invention, the distance between the injection and extraction waveguide 110 ′ and the micro-resonator 120 ′ is for example around 50 nm, between 70 nm and 30 nm (distance measured edge to edge) .
    FIGS. 4A and 4B represent the transmission spectra around the resonance wavelength of a gas sensor according to the prior art as described in the introduction, respectively of a gas sensor according to the invention such that 'illustrated in figure 3.
    In both cases, the injection and extraction waveguide and the micro-resonator are made of silicon, with a refractive index n h = 3.4, and the analysis beam is centered on approximately 4.3 μm. , to measure a concentration of carbon dioxide (CO2) in the surrounding environment.
    In order to facilitate understanding of the invention, the case of a broad spectrum analysis beam has been shown here.
    In both cases, the micro-resonator has a reduced external diameter, preferably less than 20 μm, and even less than 10 μm.
    The two micro-resonators have a resonance of the same quality factor, which corresponds to the same respective residence times of the photons in the microresonators.
    It is noted that the minimum quality factor is here limited by the curvature losses.
    FIG. 4A corresponds to the gas sensor according to the prior art.
    The abscissa axis is graduated in pm, and corresponds to a wavelength.
    The ordinate axis is unitless, and corresponds to a transmission rate ranging from
    Where 1.
    Curve 41A corresponds to a CO2 concentration of 0 ppm (parts per million), and has a minimum transmission of about 0.1 to about 4.32 pm.
    Curve 42A corresponds to a CO2 concentration of 1000 ppm, and has a minimum transmission of about 0.15 to about 4.32 pm.
    The variation in the transmission rate between the 0 ppm and 1000 ppm concentrations is 3.24%.
    The variation in transmission rate between the 0 ppm and 100 ppm concentrations was also determined, which is 0.34%.
    FIG. 4B corresponds to the gas sensor according to the invention.
    Curve 41B corresponds to a CO2 concentration of 0 ppm, and has a minimum transmission of 0.1 to about 4.33 pm.
    Curve 42B corresponds to a CO2 concentration of 1000 ppm, and has a minimum transmission from 0.22 to around 4.33 pm.
    The variation in the transmission rate between the 0 ppm and 1000 ppm concentrations is 10.23%.
    The variation in transmission rate between the 0 ppm and 100 ppm concentrations was also determined, which is 1.15%.
    Thus, for each gas concentration, the variation in the transmission rate at the resonance wavelength, between said gas concentration and a zero concentration of this gas, is multiplied by 3 thanks to the invention.
    The invention therefore makes it possible to improve the sensitivity of a gas sensor. The sensitivity is increased by a factor at least equal to 3, in comparison with a sensor of the same type according to the prior art.
    FIG. 5 illustrates a second embodiment of a biological or chemical sensor 1000 'according to the invention, comprising an optical device 100' 'according to the invention.
    The optical device 100 '' corresponds to the optical device described with reference to FIG. 2, except that it has, instead of the injection and extraction guide, an injection wave guide 110i and a wave guide d IIO2 extraction distinct from each other.
    Here, the injection waveguide 110i and the extraction waveguide IIO2 are parallel to each other, and both coupled to the micro-resonator 120 by evanescent coupling.
    The light source 200 is arranged at the input of the injection waveguide 110i.
    A first photo-detector 300i, optional, is disposed here at the output of the injection waveguide 110i, for the detection of a signal as described with reference to FIG. 3. In this case, the waveguide d injection 110i can also be called injection and extraction waveguide.
    A second photo-detector 3002 is disposed at the output of the extraction waveguide IIO2. The output of the extraction waveguide IIO2 here corresponds to the end of said waveguide, arranged on the same side of the micro-resonator as the light source 200.
    In operation, the light source 200 emits the analysis beam 1200 which propagates in the injection waveguide 110i. A part of the analysis beam, at the resonance wavelength of the micro-resonator, is transferred to the micro-resonator before being coupled to the extraction waveguide IIO2 and then detected by the photodetector 3002.
    This photo-detector 3002 therefore receives only part 1330 of the analysis beam which has passed through the micro-resonator.
    The photodetector 3002 is particularly advantageous when the light source 200 is a broadband source. In this case, although the analysis beam is broadband, the photo-detector 3002 receives a monochromatic signal at the resonance wavelength of the micro-resonator. The photodetector 3002 is then more sensitive to the effect of the surrounding medium, since it receives only the wavelength affected by this medium, and which passes through the micro-resonator.
    On the contrary, the optional photo-detector 300i receives a broadband signal in which the effect of the surrounding medium, at the resonance wavelength of the microresonator, is embedded in the middle of the wavelengths not affected by said medium .
    The use of a broadband signal can be advantageous, for example when the value of the resonance wavelength of the microresonator is not precisely known, this being influenced by the composition of the surrounding medium.
    This influence, negligible in a medium with a low index such as a gaseous medium, is greater in a medium with a high index such as a liquid medium.
    The sensor 1000 ′ is therefore advantageously a sensor for identifying a chemical biological species and / or determining its concentration, in a liquid medium.
    Note that the injection and extraction waveguide 110 or 110 'mentioned with reference to FIGS. 1 to 3, the injection waveguide 110i, and the extraction waveguide IIO2, are all waveguides optically coupled by evanescence to the microresonator. These waveguides can each be designated by the term “injection and / or extraction waveguide”.
    FIG. 6 schematically illustrates an example of a method for manufacturing an optical device according to the invention, in particular a device 100 as described with reference to FIG. 1.
    On the left, the device during manufacture is shown in a sectional view.
    On the right, the device during manufacture is shown in a top view.
    The manufacturing process uses a stack called SOI (for “Silicon On Insulotor”), consisting of the following three superposed layers: a substrate 61 (for example made of silicon), an intermediate layer 62 made of silicon dioxide, and an upper layer 63 made of silicon (starting point 601, in Figure 6).
    During a first step 602, the upper layer 63 of silicon is etched over its entire thickness, here to form the injection and extraction waveguide 110 and a notched disc 64 of silicon. Each notch of the notched disc 64 corresponds to an elementary wave guide 121 of the micro-resonator.
    The method according to the invention then comprises a step 603 of etching the disc 64, over only part of its thickness. During this step 603, the disc 64 is etched in a central region thereof, to form the micro-resonator 120.
    The etching retains a small thickness of the central region of the disc 64, which makes it possible to ensure the mechanical strength of the micro-resonator 120, and in particular to keep the elementary waveguides 121 integral with one another.
    According to a variant not shown, one engraves, in step 602, a full disc (and not a notched disc). In step 603, the solid disc is etched over part of its thickness, in a central region and in annular regions thereof. The elementary waveguides are thus formed in step 603, arranged here on a residual disc of small thickness.
    Finally, in a step 604, the intermediate layer 62 is etched over its entire thickness to form a cavity 65 under the micro-resonator 120 and the injection and extraction waveguide 110. The etching preserves, under the micro-resonator 120, a pillar 66 for holding the micro-resonator 120 suspended above the substrate 61. The pillar 66 is approximately centered on the center of the micro-resonator 120.
    The intermediate layer remaining around the cavity 65 is used in particular for the mechanical maintenance of the injection and extraction waveguide 110, in suspension above the substrate 61.
    The engraving here is a wet engraving over time.
    Each of the engravings preferably uses an etching mask.
    In practice, the various elementary waveguides of a micro-resonator according to the invention are therefore advantageously connected together by a thin thickness of material, which extends at least in a central region of the micro-resonator. This thin thickness of material can extend directly under the micro-resonator, under a central region thereof and even under the elementary waveguides.
    The micro-resonator is supported on a central pillar starting from the center of this thin thickness of material. Preferably, the width of the central pillar is at least two times less than that of the micro-resonator.
    The invention is not limited to the examples described above, and many variants can be made without departing from the scope of the invention.
    For example, the elementary waveguides are not arranged in the form of a ring, but in another form of closed loop.
    For example, the arrangement of the elementary waveguides may be in the form of two half-rings connected by two segments, or four quarter rings connected by four segments.
    The optical device according to the invention can also comprise a plurality of micro-resonators according to the invention, optically coupled together by an evanescent coupling.
    The sensor comprising such an optical device can be a gas sensor, or any other chemical element in a gaseous or liquid medium. It is in particular a concentration sensor, for example a CO2 concentration sensor in a gaseous medium, or a glucose concentration sensor in a liquid medium.
    The light source and the photo-detector of the sensor according to the invention can be integrated with the optical device on the same substrate, or remote.
    In Figures 3 and 5, there is shown the example of sensors in which the elementary waveguides are straight sections. As a variant, they can take the form of rounded sections, as in FIG. 1.
    权利要求:
    Claims (15)
    [1" id="c-fr-0001]
    1. Optical device (100; 100 '; 100' ') for a biological or chemical sensor, comprising:
    a waveguide micro-resonator (120; 120 '; 120' '), arranged to guide a light beam along a closed-loop optical path (20); and at least one injection and / or extraction waveguide (110; 110 '; 110i, IIO2), optically coupled to the micro-resonator for the injection and / or extraction of said light beam;
    characterized in that the micro-resonator (120; 120 '; 120' ') consists of a plurality of elementary waveguides (121; 121') spaced from one another, and arranged one after the other others in a loop-like arrangement.
    [2" id="c-fr-0002]
    2. Device (100; 100 '; 100' ') according to claim 1, characterized in that the elementary waveguides (121; 121') are each made of a single material.
    [3" id="c-fr-0003]
    3. Device (100; 100 '; 100' ') according to claim 1 or 2, characterized in that the elementary waveguides (121; 121') all have the same dimensions.
    [4" id="c-fr-0004]
    4. Device (100; 100 '; 100' ') according to any one of claims 1 to 3, characterized in that the elementary waveguides (121; 12Γ) are distributed periodically one after the other others, according to a regular step (P) says no distribution.
    [5" id="c-fr-0005]
    5. Device (100; 100 '; 100' ') according to claim 4, characterized in that the distribution pitch (P) is less than the central wavelength of the light beam guided in the micro-resonator.
    [6" id="c-fr-0006]
    6. Device (100; 100 '; 100' ') according to claim 5, characterized in that the distribution pitch (P) is less than:
    λ
    2n h with λ the central wavelength of the light beam guided in the micro-resonator (120; 120 ';120''); and n h the average refractive index of the elementary waveguides (121; 121 ').
    [7" id="c-fr-0007]
    7. Device (100; 100 '; 100' ') according to any one of claims 4 to 6, characterized in that the ratio between the length (Z) of an elementary waveguide (121; 12Γ), and the distribution pitch (P) is between 0.40 and 0.60.
    [8" id="c-fr-0008]
    8. Device (100; 100 '; 100' ') according to any one of claims 1 to 7, characterized in that the injection and / or extraction waveguide (110; 110'; 110i, IIO2) is made of the same material as the elementary waveguides (121; 12Γ).
    [9" id="c-fr-0009]
    9. Device (100; 100 '; 100' ') according to any one of claims 1 to 8, characterized in that the elementary waveguides (121; 121') each have the same width (w), and in that the width (w) of the elementary waveguides is strictly greater than the width (V /) of the injection and / or extraction waveguide (110; 110 '; 110i, IIO2).
    [10" id="c-fr-0010]
    10. Device (100; 100 '; 100' ') according to claim 9, characterized in that the ratio of the width (w) of the elementary waveguides (121; 121'), divided by the width (V / ) of the injection and / or extraction waveguide (110; 110 '; 110i, IIO2), is between 1.8 and 2.2.
    [11" id="c-fr-0011]
    11. Device (100; 100 '; 100' ') according to claim 9 or 10, characterized in that the width (w) of the elementary waveguides (121; 12Γ) and the width (V /) of the guide d injection and / or extraction wave (110; 110 '; 110i, IIO2) are adapted so that the injection and / or extraction waveguide has a guided mode of effective index equal to the effective index d '' a guided mode of the micro-resonator, to within 10%.
    [12" id="c-fr-0012]
    12. Device (100; 100 '; 100 ”) according to any one of claims 1 to 11, characterized in that the micro-resonator (120; 120'; 10”) and the injection waveguide and / or extraction (110; 110 '; 110i, IIO2) are spaced from each other.
    [13" id="c-fr-0013]
    13. Biological or chemical sensor (1000; 1000 '), characterized in that it comprises: a light source (200), for the emission of a light beam called the analysis beam (1200);
    an optical device (100; 100 ', 100 ”) according to any one of claims 1 to 12, in which one of the at least one injection and / or extraction waveguide (110; 110' ; 110i) is arranged to receive the analysis light beam (1200), andtransfer to the micro-resonator at least a part (1220) of the analysis light beam, at a resonance wavelength of the microresonator; and at least one photo-detector (300; 300i; 3ΟΟ2), arranged to receive a light beam (1300; 1330) emitted at the output of said optical device, and resulting from the coupling between said injection and / or extraction waveguide (110; 110 '; 110i; IIO2) and the micro-resonator (120; 120'; 120 ”).
    [14" id="c-fr-0014]
    14. Biological or chemical sensor (1000) according to claim 13, characterized in that the optical device (100; 100 '; 100 ”) comprises an injection and / or extraction waveguide (110; 110'; 110i ), and in that :
    the light source (200) is arranged at the input of the injection and / or extraction waveguide (110; 110 '; 110i); and one of the at least one photo-detector (300; 300i) is disposed at the output of the injection and / or extraction waveguide (110; 110 '; 110i), arranged to receive a signal (1300 ) corresponding to what remains of the analysis light beam (1200) after transit through the micro-resonator of at least part of the analysis light beam.
    [15" id="c-fr-0015]
    15. Biological or chemical sensor (1000) according to claim 13 or 14, characterized in that the optical device (100; 100 '; 100' ') comprises an injection waveguide (110i) and a guide extraction wave (IIO2), and in that:
    5 - the light source (200) is arranged at the input of the injection waveguide (110i); and one of the at least one photo-detector (3ΟΟ2) is disposed at the output of the extraction waveguide (IIO2), arranged to receive a signal (1330) corresponding to what remains of the part of the beam analysis transferred to the micro-resonator,
    10 after transit through said micro-resonator.
    S.60755
    1/4
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    同族专利:
    公开号 | 公开日
    US20180039024A1|2018-02-08|
    EP3276337B1|2020-09-02|
    FR3054664B1|2018-09-07|
    EP3276337A1|2018-01-31|
    US10677988B2|2020-06-09|
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    法律状态:
    2017-07-31| PLFP| Fee payment|Year of fee payment: 2 |
    2018-02-02| PLSC| Publication of the preliminary search report|Effective date: 20180202 |
    2018-07-27| PLFP| Fee payment|Year of fee payment: 3 |
    2019-07-31| PLFP| Fee payment|Year of fee payment: 4 |
    2020-07-31| PLFP| Fee payment|Year of fee payment: 5 |
    2021-07-29| PLFP| Fee payment|Year of fee payment: 6 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1657222|2016-07-27|
    FR1657222A|FR3054664B1|2016-07-27|2016-07-27|SEGMENTED RING MICRO RESONATOR OPTICAL DEVICE FOR BIOLOGICAL OR CHEMICAL SENSOR|FR1657222A| FR3054664B1|2016-07-27|2016-07-27|SEGMENTED RING MICRO RESONATOR OPTICAL DEVICE FOR BIOLOGICAL OR CHEMICAL SENSOR|
    EP17182954.2A| EP3276337B1|2016-07-27|2017-07-25|Optical device with segmented-ring micro-resonator|
    US15/660,251| US10677988B2|2016-07-27|2017-07-26|Optical device with segmented ring microresonator|
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